$A$ and $B$ are Morita equivalent if they are equivalent objects in this bicategory. Equivalence classes $[A]$ form an abelian monoid whose multiplication is given by the monoidal product. The super Brauer group of $\mathbb{R}$ is the subgroup of invertible elements of this monoid.
If $[B]$ is inverse to [A] in this monoid, then in particular $A \otimes (-)$ can be considered left biadjoint to $B \otimes (-)$. On the other hand, in the bicategory above we always have a biadjunction $$ \begin{array}{ccl} A \otimes C \to D \\ ------ \\ C \to A^* \otimes D \end{array} $$ essentially because left $A$-modules are the same as right $A^*$-modules, where $A^*$ denotes the super algebra opposite to $A$. Since right biadjoints are unique up to equivalence, we see that if an inverse to $[A]$ exists, it must be $[A^*]$. This can be sharpened: an inverse to $[A]$ exists iff the unit and counit $$ 1 \to A^* \otimes A \qquad A \otimes A^* \to 1 $$ are equivalences in the bicategory. Actually, one is an equivalence iff the other is, because both of these canonical 1-morphisms are given by the same $A$-bimodule, namely the one given by $A$ acting on both sides of the underlying superspace of $A$ (call it $S$) by multiplication. Either is an equivalence if the bimodule structure map $$ A^* \otimes A \to \mathrm{Hom}(S, S), $$ which is a map of superalgebras, is an isomorphism.
One manifestation of Bott periodicity is that $[\mathrm{Cliff}_1]$ has order 8. We will soon see a very easy proof of this fact. A theorem of C. T. C. Wall is that $[\mathrm{Cliff}_1]$ in fact generates the super Brauer group; I believe this can be shown by classifying super division algebras, as discussed below.
$\mathrm{Cliff}_3$ has three supercommuting odd elements $i, j, l,$ all of which are square roots of $-1$. It follows that $e = i j l$ is an odd central involution (here 'central' is taken in the ungraded sense), and also that $i' = j l$, $j' = l i$, $k' = i j$ satisfy the Hamiltonian equations $$ (i')^2 = (j')^2 = (k')^2 = i'j'k' = -1, $$ so we have $\mathrm{Cliff}_3 = \mathbb{H}[e]/\langle e^2 - 1\rangle$. Note this is the same as $$ \mathbb{H} \otimes \mathrm{Cliff}_1^* $$ where the $\mathbb{H}$ here is the quaternions viewed as a super algebra concentrated in degree 0 (i.e. is purely bosonic).
Then we see immediately that $\mathrm{Cliff}_4 = \mathrm{Cliff}_3 \otimes \mathrm{Cliff}_1$ is equivalent to purely bosonic $\mathbb{H}$ (since the $\mathrm{Cliff}_1$ cancels $\mathrm{Cliff}_1^\ast$ in the super Brauer group).
At this point we are done: we know that conjugation on (purely bosonic) $\mathbb{H}$ gives an isomorphism $$ \mathbb{H}^* \cong \mathbb{H} $$ hence $[{\mathbb{H}}]^{-1} = [\mathbb{H}^*] = [\mathbb{H}]$, i.e. $[\mathbb{H}] = [\mathrm{Cliff}_4]$ has order 2! Hence $[\mathrm{Cliff}_1]$ has order 8.
For the record, then, here are the hours of the super Brauer clock, where $e$ denotes an odd element, and $\simeq$ denotes Morita equivalence: $$ \begin{array}{ccl} \mathrm{Cliff}_0 & \simeq & \mathbb{R} \\ \mathrm{Cliff}_1 & \simeq & \mathbb{R} + \mathbb{R}e, \quad e^2 = -1 \\ \mathrm{Cliff}_2 & \simeq & \mathbb{C} + \mathbb{C}e, \quad e^2 = -1, e i = -i e \\ \mathrm{Cliff}_3 & \simeq & \mathbb{H} + \mathbb{H}e, \quad e^2 = 1, e i = i e, e j = j e, e k = k e \\ \mathrm{Cliff}_4 & \simeq & \mathbb{H} \\ \mathrm{Cliff}_5 & \simeq & \mathbb{H} + \mathbb{H}e, \quad e^2 = -1, e i = i e, e j = j e, e k = k e \\ \mathrm{Cliff}_6 & \simeq & \mathbb{C} + \mathbb{C} e, \quad e^2 = 1, e i = -i e \\ \mathrm{Cliff}_7 & \simeq & \mathbb{R} + \mathbb{R}e, \quad e^2 = 1 \end{array} $$ All the superalgebras on the right are in fact division superalgebras, i.e. superalgebras in which every nonzero homogeneous element is invertible.
To prove Wall's result that $[\mathrm{Cliff}_1]$ generates the super Brauer group, we need a lemma: any element in the super Brauer group is the class of a central division superalgebra: that is, one with $\mathbb{R}$ as its center.
Then, if we classify the division superalgebras over $\mathbb{R}$ and show the central ones are Morita equivalent to $\mathrm{Cliff}_0, \dots, \mathrm{Cliff}_7$, we'll be done.
The key observation is that for any $a \in A$, there exists a unique $a' \in A$ such that $$ a e = e a' $$ and that the $A$-bimodule structure forces $(a b)' = a'b'$. Hence we have an automorphism (fixing the real field) $$ (-)': A \to A $$ and we can easily enumerate (up to isomorphism) the possibilities for associative division superalgebras over $\mathbb{R}$:
For the identity automorphism, we can adjust $e$ so that $\langle e, e \rangle$ is 1. This gives the super algebra $\mathbb{C}[e]/\langle e^2 - 1\rangle$ (where $e$ commutes with elements in $\mathbb{C}$). This does not occur on the super Brauer clock over $\mathbb{R}$. However, it does generate the super Brauer group over $\mathbb{C}$ (which is of order two).
This appears to be a complete (even if a bit pedestrian) analysis.